School of Egineering and Engineering Technology

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Browsing School of Egineering and Engineering Technology by Subject "Adsorption kinetic models"

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    Adsorption kinetics and Mechanisms of cypermethrin and dichlorovos on heterogeneous activated carbon porous media
    (Federal University of Technology, Owerri, 2015-11-18) Atulegwu, Patrick Uzoije; Kamalu, Clinfford O.; Uzuakpundu, Basil
    Adsorption kinetics and mechanism of Cypermethrin (CY) and Dichlorovos (DI) on activated car bons of oil bean seed shell (OBSS), unripe plantain peel (UPP) and castor bean seed shell (CBSS) systems have been studied. The equilibrium adsorption isotherms were modelled by Freunlich, Langmuir and Langmuir-Freunlich (LF) models. Adsorption isotherms of various systems were best described by Langmuir-Freunlich (LF). Mixed 1,2 order equation (MOE), integrated kinetic Langmuir (IKL), pseudo second order equation (PSOE), fractal-like mixed 1,2 order equation (F-MOE), and Boyd and Webbers models were compared and adopted in the analysis of the kinetic data. The models represented different uptake reduction rate of CY and DI by various adsorption systems. F-MOE, IKL and MOE models were in agreement with CY/OBSS, CY/UPP and CY/CBSS sys tem data respectively, hence the conforming models, whereas IKL, MOE and PSOE were the con forming models for DI/OBSS, DI/UPP and DI/CBSS adsorption data systems, respectively. The two diffusion models (Boyd and Webbers) applied confirmed film diffusion pattern as prevailing transportation pathway for CY and DI onto the adsorbents.