Browsing by Author "Obijiaku, J. C."
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Item Open Access Curve-fitting of bioremediation of polycyclic aromatic hydrocarbons (PAHs) by co-composting using roost manure(EverScience Publications, 2016) Kamalu, C. I. O.; Nwakaudu, A. A.; Onyelucheya, O. E.; Uzondu, F. N.; Kamen, F. L.; Nwakaudu, M. S.; Obijiaku, J. C.In this work, ten polluted sites with oil were obtained from Niger Delta, mixed homogenously with compost manure and sent to FUGRO International Laboratory Port Harcourt Nigeria, for bioremediation experiments and analyses. The 4800g sample was divided into twelve (12) equal parts of 400g for bioremediation; 6 parts for the experiments and 6 parts for the control. Particular ringed PAH was isolatedly tested for bioremediation for each of the five ringed PAHs (1 to 5 rings) and the 800g sample was used for respiration test of compost incubation. It was found that the efficiency of bioremediation increased from one to three rings and decreased exponentially for the rest of the rings, showing that bioremediation is not effective for higher ring PAHs. It was also found that bioremediation yields best (optimum) result between two and three ringed PAHs. The respiration of the compost microorganisms improved during incubation by more than two-third i.e 67.7%. The result of this work can be used in bioremediation studies when trying to isolate or choose a particular ringed PAHs for such bioremediation jobs.Item Open Access Effects of extraction techniques on the yield and mechanical properties of empty plantain fruit bunch fibers(Vandana Publications, 2015-12) Obijiaku, J. C.; Kamalu, C. I. O.; Osoka, E. C.; ,Onyelucheya, O. E.; Uzondu, F. N.; Obibuenyi, J. I.Two major techniques; water retting and dew retting, were used to extract natural fiber from empty plantain fruit bunch. Four different size categories each comprising of a group of six (6) bunches were used for the water retting experiments and two size categories each of six (6) bunch samples were used for the dew retting experiments. Results for the water retting experiment showed that the fiber yield is enhanced by the addition of a load/weights on the retting bunch and the bunch size, while results for the dew retting revealed that fiber yield is dependent on both retting time and bunch size. Results of statistical analysis produced optimum yield value of 85.95% with a maximum dded weight of 5kg and bunch diameter size of 4cm for the water retting, and for dew retting, an optimum yield value of 60.38% for the bigger bunch size of 5.5cm when extracted on the same day of harvest. Mechanical tests on fiber from the two techniques showed better mechanical properties for the water retting categories with a maximum tensile strength of 823.295N/mm2 and modulus of elasticity (MOE) of 644.318N/mm2. The fiber extracted finds use in the manufacture of reinforced composite materials which are fast replacing the use of metallic and plastic materials, due to the quest for materials that are light and cheap, yet strong.Item Open Access Modeling the kinetics of photosynthetic chemistry(U. P., 2015-11) Kamalu, C. I. O.; Nwakaudu, M. S.; Obijiaku, J. C.; Okwara, C. A.; Kamen, F. L.; Uzondu, F. N.; Osoka, E. C.In this work, the chemical kinetics of photosynthesis was extensively explored. Kinetic models were established. Existing data from the internet were used for the validation of the models. It was observed that the models are real and natural as they follow the growth profile nature of photosynthetic release, together with the uptake of oxygen and carbon dioxide respectively. The models actually conform to what was found in literature. Therefore photosynthetic activities could be studied using natural growth models, in conjunction with the specificities of photosynthetic phenomena. This work can be employed in the growth study of plants in agriculture, carbon cycle, and perhaps ozone layer depletion or carbon sequestration.Item Open Access Predictive modeling of Nigerian peak condensate using Hubbert’s zero annual reserve rate(Vandana Publications, 2015) Kamalu, C. I. O.; Appah, D.; Obah, B.; Anyanwu, E. E.; Obijiaku, J. C.; Uzondu, F. N.; Okolie, I. J.; Oghome, P.In this work, a model was developed using Kamalu’s (2010) natural resource depletion word equation in one hand and Hubbert zero rate of annual reserve concept on the other hand. Experimental data was collected from Nigerian Ministry of Petroleum and Minerals, 7 Kofo Abayomi Street, Victoria Island, Lagos to validate the model. It gave coefficient of correlation of 0.99997 and 0.99517 for discovery and production of Nigerian condensate respectively. It was also established that Nigerian condensate will exhaust in the year 2518 AD when the discovery and production values will be equal to 110MMB. The research reveals that there is a gentle interaction between the cumulative discovery and production and serious interaction between annual discovery and production as years roll by. This work can be used by Nigerian government to plan their condensate budget both nationally and internationally and to cushion their position in OPEC and the world